The author of 《meta-Selective C-H Activation of Arenes at Room Temperature Using Visible Light: Dual-Function Ruthenium Catalysis》 were Sagadevan, Arunachalam; Greaney, Michael F.. And the article was published in Angewandte Chemie, International Edition in 2019. HPLC of Formula: 301673-14-3 The author mentioned the following in the article:
Ruthenium-catalyzed meta-C-H activation of arenes at room temperature is reported to proceed under blue-light irradiation A variety of heteroarenes are compatible with this photochem. process, which leads to the corresponding meta C-C coupling products in good to very good yields. Initial mechanistic studies suggest a single-electron transfer process occurs between a photoexcited RuII-cyclometalated complex and alkyl halides, enabling meta-C-H functionalization reaction via carbon-centered radicals.tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3HPLC of Formula: 301673-14-3) was used in this study.
tert-Butyl 4-iodopiperidine-1-carboxylate(cas: 301673-14-3) is one of organic iodides. Alkyl iodides react at a faster rate than alkyl fluorides due to the weak C-I bond. Iodo alkanes participate in a variety of organic synthesis reactions, which include the SimmonsSmith reaction (cyclopropanation using iodomethane), Williamson ether synthesis, Wittig reaction, Grignard reaction, alkyl coupling reactions, and Wurtz reaction.HPLC of Formula: 301673-14-3
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com