Koo, Seung Moh; Vendola, Alex J.; Momm, Sarah Noemi; Morken, James P. published the artcile< Alkyl Group Migration in Ni-Catalyzed Conjunctive Coupling with C(sp3) Electrophiles: Reaction Development and Application to Targets of Interest>, Recommanded Product: tert-Butyl (3-iodopropyl)carbamate, the main research area is alkyl migration cross coupling nickel catalyst; organoboronic ester preparation cross coupling nickel catalyst; coniine indolizidine 209D preparation cross coupling nickel catalyst.
A catalytic conjunctive cross-coupling reaction was developed that allows the construction of chiral organoboronic esters from alkylboron ate complexes and alkyl iodide electrophiles. The process occurs most efficiently with a Ni/Pybox-comprised catalyst and with an acenaphthoquinone-derived boron ligand. Because of the broad functional group tolerance of this reaction, it can be a versatile tool for organic synthesis. Applications to the construction of (R)-coniine and (-)-indolizidine 209D are described.
Organic Letters published new progress about Boronic acids, esters Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 167479-01-8 belongs to class iodides-buliding-blocks, and the molecular formula is C8H16INO2, Recommanded Product: tert-Butyl (3-iodopropyl)carbamate.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com