In 2022,Kittikhunnatham, Preecha; Leith, Gabrielle A.; Mathur, Abhijai; Naglic, Jennifer K.; Martin, Corey R.; Park, Kyoung Chul; McCullough, Katherine; Jayaweera, H. D. A. Chathumal; Corkill, Ryan E.; Lauterbach, Jochen; Karakalos, Stavros G.; Smith, Mark D.; Garashchuk, Sophya; Chen, Donna A.; Shustova, Natalia B. published an article in Angewandte Chemie, International Edition. The title of the article was 《A Metal-Organic Framework (MOF)-Based Multifunctional Cargo Vehicle for Reactive-Gas Delivery and Catalysis》.Category: iodides-buliding-blocks The author mentioned the following in the article:
The efficient delivery of reactive and toxic gaseous reagents to organic reactions was studied using metal-organic frameworks (MOFs). The simultaneous cargo vehicle and catalytic capabilities of several MOFs were probed for the first time using the examples of aromatization, aminocarbonylation and carbonylative Suzuki-Miyaura coupling reactions. These reactions highlight that MOFs served a dual role as a gas cargo vehicle and a catalyst, led to product formation with yields similar to reactions employing pure gases. Furthermore, the MOFs was recycled without sacrificing product yield, while simultaneously maintaining crystallinity. The reported findings were supported crystallog. and spectroscopically (e.g., diffuse reflectance IR Fourier transform spectroscopy), foreshadowing a pathway for the development of multifunctional MOF-based reagent-catalyst cargo vessels for reactive gas reagents as an attractive alternative to the use of toxic pure gases or gas generators. The results came from multiple reactions, including the reaction of 4-Chloro-2-iodoaniline(cas: 63069-48-7Category: iodides-buliding-blocks)
4-Chloro-2-iodoaniline(cas: 63069-48-7) belongs to anime. Reaction with nitrous acid (HNO2), which functions as an acylating agent that is a source of the nitrosyl group (―NO), converts aliphatic primary amines to nitrogen and mixtures of alkenes and alcohols corresponding to the alkyl group in a complex process. This reaction has been used for analytical determination of primary amino groups in a procedure known as the Van Slyke method.Category: iodides-buliding-blocks
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com