Kakuchi, Ryohei; Fukasawa, Kota; Kikuchi, Moriya; Narumi, Atsushi; Kawaguchi, Seigou; Li, Yao; Kim, Hyung; Amii, Hideki published their research in Macromolecules (Washington, DC, United States) in 2021. The article was titled 《Computer-aided design of postpolymerization modification reaction based on aminolysis of α,α-difluoroacetate esters》.Electric Literature of C7H5IO The article contains the following contents:
A new postpolymn. protocol based on the reactivity of α,α-difluoroacetate esters is proposed and rationalized via a combined effort of computational and exptl. methods. Reaction systems designed on the basis of computational results are characterized in detail. It is found that aminolysis of polymers featuring α,α-difluoroacetate esters results in a 100% conversion of ester units to α,α-difluoroacetamide derivatives This indicates that the new activated ester-amine chem. reported here offers a promising approach to postpolymn. modifications. After reading the article, we found that the author used 4-Iodobenzaldehyde(cas: 15164-44-0Electric Literature of C7H5IO)
4-Iodobenzaldehyde(cas: 15164-44-0) is used in synthesis of 4-[2-(trimethylsilyl)ethynyl]benzaldehyde, 5,15-dimesityl-10-(3-[2-(trimethylsilyl)ethynyi]phenyl}-20-(4-iodophenyl)porphyrin, and 5,15-dimesityl-10-[3,5-bis{2-[4-(N,N’-difluoroboryl-1,9-dimethyidipyrrin-5-yl)-phenyl]ethynyl}phenyl]-20-(4-iodophenyl)porphyrin.Electric Literature of C7H5IO
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com