Safety of 1-Bromo-3-iodobenzeneIn 2019 ,《Rhodium catalyzed synthesis of seleno-ketals via carbene transfer reactions of diazoesters》 was published in Chemical Communications (Cambridge, United Kingdom). The article was written by Jana, Sripati; Aseeva, Polina; Koenigs, Rene M.. The article contains the following contents:
Herein, rhodium catalyzed carbene transfer reactions of diazoesters with diselenides that result in the formal insertion reaction of the carbene fragment into the Se-Se bond to give seleno-ketals in up to 96% yield (35 examples) via an ionic mechanism is described. After reading the article, we found that the author used 1-Bromo-3-iodobenzene(cas: 591-18-4Safety of 1-Bromo-3-iodobenzene)
1-Bromo-3-iodobenzene(cas: 591-18-4) has been used in the preparation of 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene.Safety of 1-Bromo-3-iodobenzene
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com