D’Auria, Maurizio; Piancatelli, Giovanni; Ferri, Tommaso published the artcile< Photochemical reactivity of halofuran and halothiophene derivatives in the presence of arylalkenes and arylalkynes>, Name: Methyl 5-iodothiophene-2-carboxylate, the main research area is photochem substitution iodothiophene vinylarene ethynylarene; halofuran photochem substitution vinylarene; ethylene furyl thienyl.
Photochem. reactions of 5-iodo-2-thiophenecarboxaldehyde, 2-acetyl-5-iodothiophene (I), and 5-bromo- and 5-iodo-2-furancarboxaldehyde with styrene, 2-vinylthiophene and -furan (II), 4-methyl-5-vinyl-1,3-thiazole, and benzofuran are described. All the reactions give the substitution products as cis-trans mixtures E.g., I and II give a 1:1 cis-trans mixture of furylthienylethylene III. Reactions of iodothiophenes with ethynylarenes are also described; products resulting from substitution on the CCH group or on the thiophene ring are both obtained. The mechanism of the reactions is discussed in terms of an electron-transfer process.
Journal of Organic Chemistry published new progress about Photosubstitution reaction. 88105-22-0 belongs to class iodides-buliding-blocks, and the molecular formula is C6H5IO2S, Name: Methyl 5-iodothiophene-2-carboxylate.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com