Wang, Lei; Byun, Jeehye; Li, Run; Huang, Wei; Zhang, Kai A. I. published the artcile< Molecular Design of Donor-Acceptor-Type Organic Photocatalysts for Metal-free Aromatic C-C Bond Formations under Visible Light>, Application of C7H3FIN, the main research area is mol Donor Acceptor organic photocatalysts metal free aromatic carbon.
Metal-free and photocatalytic radical-mediated aromatic C-C bond formations offer a promising alternative pathway to the conventional transition metal-catalyzed cross-coupling reactions. However, the formation of aryl radicals from common precursors such as aryl halides is highly challenging due to their extremely high reductive potential. Here, we report a structural design strategy of donor-acceptor-type organic photocatalysts for visible light-driven C-C bond formations through the reductive dehalogenation of aryl halides. The reduction potential of the photocatalysts could be systematically aligned to be -2.04 V vs. SCE via a simple heteroatom engineering of the donor-acceptor moieties. The high reductive potential of the mol. photocatalyst could reduce various aryl halides into aryl radicals to form the C-C bond with heteroarenes. The design ability of the mol. photocatalyst further allowed the synthesis of a high LUMO (LUMO) polymer photocatalyst by a self-initiated free radical polymerization without compromising its LUMO level.
Advanced Synthesis & Catalysis published new progress about Cyclic voltammetry. 887266-99-1 belongs to class iodides-buliding-blocks, and the molecular formula is C7H3FIN, Application of C7H3FIN.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com