Olah, George A.; Wang, Qi; Sandford, Graham; Surya Prakash, G. K. published the artcile< Synthetic methods and reactions. 181. Iodination of deactivated aromatics with N-iodosuccinimide in trifluoromethanesulfonic acid (NIS-CF3SO3H) via in situ generated superelectrophilic iodine(I) trifluoromethanesulfonate>, Category: iodides-buliding-blocks, the main research area is iodination aromatic iodosuccinimide trifluoromethanesulfonic acid.
Deactivated aromatic compounds are readily iodinated by N-iodosuccinimide in trifluoromethanesulfonic acid (triflic acid) in good yields. Thus, PhNO2 was treated with NIS-CF3SO3H to give 3-iodonitrobenzene in 86% yield. The novel iodination is suggested to involve in situ generated and protosolvated iodine(I) trifluoromethanesulfonate.
Journal of Organic Chemistry published new progress about 2265-92-1. 2265-92-1 belongs to class iodides-buliding-blocks, and the molecular formula is C6H3F2I, Category: iodides-buliding-blocks.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com