Chen, Yuhang; Zhang, Dingcheng; Sun, Mingze; Ding, Zhenhua published the artcile< Divergent synthesis of isoxazoles and 6H-1,2-oxazines via hypervalent iodine-mediated intramolecular oxygenation of alkenes>, Electric Literature of 1391728-13-4, the main research area is isoxazoles preparation; oxazine preparation; alkene intramol oxygenation hypervalent iodine mediated.
The divergent synthesis of isoxazoles I [R1 = Ph, 4-MeC6H4, 2-naphthyl, etc.; R2 = Ph, 2-naphthyl, 2-furyl, etc.] and 6H-1,2-oxazines II [R3 = Me, CH(Me)2, cyclohexyl, Bn; Ar = Ph, 4-FC6H4, 2-naphthyl, etc.] was realized using a hypervalent fluoroiodane reagent from β,γ-unsaturated oximes. The formation of a five- or six-membered ring is controlled by the substituents of the substrates combined with the reaction conditions. The reaction was performed under mild conditions and gave the products in moderate to good yields.
New Journal of Chemistry published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 1391728-13-4 belongs to class iodides-buliding-blocks, and the molecular formula is C9H10FIO, Electric Literature of 1391728-13-4.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com