In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. COA of Formula: C6H6IN.
Himmelbauer, Daniel;Schratzberger, Heiko;Kaefer, Matthias G.;Stoeger, Berthold;Veiros, Luis F.;Kirchner, Karl research published 《 Nonsymmetrical Benzene-Pyridine-Based Nickel Pincer Complexes Featuring Borohydride, Formate, Ethyl, and Nitrosyl Ligands》, the research content is summarized as follows. Nonsym. Ni PCN pincer complexes [Ni(iPrPCNX)Cl] (X = NMe, CH2) were obtained by metalation of the benzene-pyridine-based pincer ligand iPrPCNX (X = NMe, CH2) with [Ni(dme)Cl2] (dme = 1,2-dimethoxyethane). These Ni species afforded the resp. borohydride and Et complexes [Ni(iPrPCNX)L] (L = BH4, Et) upon treatment with NaBH4 and EtMgBr (or Et2Mg), resp. Reacting [Ni(iPrPCNX)(κ2-BH4)] with CO2 gave the formate complexes [Ni(iPrPCNX)(OCHO)]. Treatment of [Ni(iPrPCNX)Cl] with the nitrosyl salt NOBF4 gave the unusual cationic square-pyramidal Ni nitrosyl pincer complexes [Ni(iPrPCNX)(NO)Cl]+ featuring a strongly bent NO ligand (∠Ni-N-O 128.5°). These systems can be described as {NiNO}10 according to the Enemark-Feltham convention. Despite of the bent nature of the NO ligand the νNO is observed at 1849 cm-1 which is more typical for a linear Ni-N-O arrangement. The structure of these complexes is rationalized by DFT calculations The mol. structures of representative complexes are presented.
COA of Formula: C6H6IN, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.
3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com