In general, organic iodides are light-sensitive and turn yellow during storage, owing to the formation of iodine. 626-01-7, formula is C6H6IN, Name is 3-Iodoaniline.Organic iodides can be alkyl, alkenyl, or alkynyl, and all of them are very reactive toward with many kinds of nucleophiles. Formula: C6H6IN.
Gurskaya, Larisa Yu.;Polienko, Yuliya F.;Rybalova, Tatyana V.;Gritsan, Nina P.;Dmitriev, Alexey A.;Kazantsev, Maxim S.;Zaytseva, Elena V.;Parkhomenko, Dmitry A.;Beregovaya, Irina V.;Zakabluk, Galina A.;Tretyakov, Evgeny V. research published 《 Multispin Systems with a Rigid Ferrocene-1,1′-diyl-Substituted 1,3-Diazetidine-2,4-diimine Coupler: A General Approach》, the research content is summarized as follows. This paper describes the stepwise aza-Wittig reaction of 1,1′-bis(triphenylphosphoranylidenamino)-ferrocene with a paramagnetic isocyanate, namely, 3-isocyanato-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrole-1-oxyl, and then with substituted aryl isocyanates. The intermediate product (a paramagnetic betaine), which is the product of an intramol. nucleophilic attack of the nitrogen atom of the iminophosphorane moiety on the carbon atom of the carbodiimide functional group, was isolated and structurally characterized. Subsequent interaction of the betaine with aryl isocyanates under mild conditions gave spin-labeled ferrocenophanes with the 1,3-diazetidine-2,4-diimine coupler. It was found that the mutual arrangement of the substituents in the latter depends on the nature of the substituents in the aryl isocyanate. Iodophenyl derivatives of 1,3-diazetidine-2,4-diimines were cross-coupled with the gold(I) nitronyl nitroxide-2-ide complex, thus yielding diradicals: metallocenophanes functionalized with various types of nitroxide substituents. Mol. and crystal structures of all mono- and diradicals were solved by x-ray diffraction anal.
Formula: C6H6IN, 3-Iodoaniline is a useful research compound. Its molecular formula is C6H6IN and its molecular weight is 219.02 g/mol. The purity is usually 95%.
3-Iodoaniline is a fatty acid that is used in analytical methods to measure the concentration of human serum in blood. It can be used to estimate the population growth rate, with a half-life of about 13 hours. 3-Iodoaniline reacts with hydrogen bond and proton to form a reaction solution, which can be catalyzed by palladium-catalyzed coupling and suzuki coupling reactions. The activation energies for these reactions are typically in the range of 4-8 kcal/mol. The chemical ionization technique is a type of mass spectrometry that is used to determine kinetic data for this compound. Hydrochloric acid can be added as an acid catalyst to increase the rate of reaction and generate more accurate kinetic data., 626-01-7.
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com