Organic iodides are organic compounds containing a carbon-iodine (C-I) bond. 1120-90-7, formula is C5H4IN, Name is 3-Iodopyridine.The carbon-iodine bond is weaker than other carbon-halogen bonds due to the poor electronegative nature of the iodine atom. Related Products of 1120-90-7.
Adler, Pauline;Dumas, Timothe;Deyris, Pierre-Alexandre;Petit, Eddy;Diliberto, Sebastien;Boulanger, Clotilde;Grison, Claude research published 《 II- from ecological recycling of Pd to greener sonogashira cross-coupling reactions》, the research content is summarized as follows. Based on a new process derived from biosorption technol. that uses roots from aquatic and wetland plants (Mentha aquatica, Eichhornia crassipes, Pistia stratiotes, Ludwigia peploides, Fallopia japonica), materials rich in lignin (pinecone, bark pine) and wastes rich in tannins (coffee grounds), we were able to prepare a new class of ecocatalyst, called Eco-Pd. The formed Eco-Pd are characterized via MP-AES and XRDP in the order to elucidate the chem. composition and the structure of the new formed materials. Interestingly, the presence of higher-oxidation-state palladium species, namely K2PdCl6, is observed We describe the use of this new generation of Eco-Pd for a green and sustainable Sonogashira reaction. The absence of copper, ligands, additives, a lower Pd loading (0.05 mol% – 0.1 mol%), the use of green solvents (glycerol/n-BuOH), and the use of biosourced Pd and base (Eco-Ca), are significant advantages of this approach. The combination TON/TOF (103/250 h-1) can be advantageously compared with literature and demonstrates the remarkable practical utility of these new catalysts. Most importantly, the Eco-Pd can be easily recycled by biosorption and reused, that is another asset in terms of sustainable Chem.
1120-90-7, 3-Iodopyridine is a heteroaryl halide. It undergoes microwave-assisted coupling with heterocyclic compounds (pyrazole, imidazole, pyrrole and indole) to afford the corresponding N-3-pyridinyl-substituted heterocyclic compounds.
3-Iodopyridine is a useful research chemical used as a reactant in the copper-catalyzed coupling of alkylamines and aryl iodides.
3-Iodopyridine is an isomeric compound that can be synthesized by cross-coupling reactions. This compound has been shown to have nicotinic acetylcholine receptor binding properties and may be useful in the treatment of Alzheimer’s disease. 3-Iodopyridine is a primary amino acid that can be used for the synthesis of amines, which are nitrogen nucleophiles. It has been crystallized with halides and its x-ray structures have been determined. The nmr spectra of 3-iodopyridine show that it contains phosphorus and nitrogen atoms. 3-Iodopyridine is also able to take up nitrate ions from solution, which may be due to its uptake properties., Related Products of 1120-90-7
Referemce:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com