The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about LCu(μ-X)2CuL compounds: An induced cuprophilic interaction, the main research direction is copper phenylphosphine cyclohexylphosphine pentafluorophenol fluoromethylmethanol fluoromethylbenzenemethanol complex preparation; mol optimization luminescence copper phenylphosphine cyclohexylphosphine pentafluorophenol fluoromethylmethanol fluoromethylbenzenemethanol; crystal structure copper phenylphosphine cyclohexylphosphine pentafluorophenol fluoromethylmethanol fluoromethylbenzenemethanol.Formula: C9H11Cu.
A trio of dimeric copper(I) complexes of the formula [(Ph3P)Cu(μ-X)2Cu(PPh3)] (X = OC6F5, 1, OC4F9, 2, OCPh(CF3)2, 3) were prepared and characterized by X-ray crystallog., elemental anal., and NMR spectroscopy (1H, 13C, 19F, 31P), as was the monomeric [(cy3P)Cu(OC4F9)] (cy = cyclohexyl, 4). Solution conductivity studies demonstrate that all three new dinuclear compounds, as well as the known [(Ph3P)Cu(μ-OC4H9)2Cu(PPh3)], 2-H, are neutral species in solution and do not rearrange into ion pairs. The fold angle (β) varies among these four dimers and the Cu(I)···Cu(I) distance in the structure of 2, 2.8315(5) Å, is cuprophilic. The Cu(I)···Cu(I) distances for 1, 2-H, and 3 are 3.0533(5), 2.890(2), and 3.0169(6) Å resp. D. functional theory (DFT) calculations were performed on 1, 2, 3, and 2-H, as well as the hypothetical 1-H, and several related models. Five PMe3 models, 1(Me), 1-H(Me), 2(Me), 2-H(Me), and 3(Me) were also studied as well as five monomers [(Me3P)CuX] 1-mon, 1-H(mon), 2-mon, 2-H(mon), and 3-mon to understand the electronic reasons for folding in this group of compounds A Natural Energy Decomposition Anal. (NEDA) indicates that electrostatic stabilizations are the dominant factor governing the strength of interaction between monomeric fragments in 1(Me)-3(Me). NBO anal. reveals that 1(Me) and 1-H(Me) do not display any cuprophilic interactions. The folding angle observed in 2(Me), 2-H(Me), and 3(Me), which is correlated with an increased delocalization from the oxygen 2pz lone pairs, brings the metal centers into sufficient propinquity to have weak Cu···Cu orbital interactions. Weak luminescence behavior at room-temperature is also consistent with these assignments.
After consulting a lot of data, we found that this compound(75732-01-3)Formula: C9H11Cu can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com