Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 75732-01-3, is researched, SMILESS is [Cu]C1=C(C)C=C(C)C=C1C, Molecular C9H11CuJournal, Chemistry of Materials called Lewis Base Adducts of Barium/Copper tert-Butoxides: Synthesis and Thermolysis of [BaCu2(OtBu)4]n and [L2Ba2Cu4(OtBu)8] (L = Me3NO and Et3PO). X-ray Crystal Structure of [(Me3NO)2Ba2Cu4(OtBu)8], Author is Borup, Bjoern; Folting, Kirsten; Caulton, Kenneth G., the main research direction is crystal structure barium copper butanolato adduct; barium copper butoxide preparation structure thermolysis; methylamine oxide barium copper butoxide preparation; phosphine oxide barium copper butoxide thermolysis; thermolysis barium copper butoxide complex adduct.Reference of Mesitylcopper(I).
Reaction of copper(I) mesityl with [Ba(OtBu)2(t-BuOH)2]4 yields insoluble [BaCu2(OtBu)4]n, which dissolves by adduct formation (L = Me3NO or Et3PO) to form soluble L2Ba2Cu4(OtBu)8. For L = Me3NO, this mol. is shown by x-ray diffraction to have a structure based on a trans-Ba2Cu4 octahedron, with all Ba/Cu edges bridged by μ2-OtBu units; one L binds to each Ba (monoclinic, space group P21/c, R = 0.0822). Bulk thermolysis, TGA, and product anal. revealed that OtBu units undergo not only O/C cleavage but also C/C cleavage, the latter to form carbonate and nonvolatile hydrocarbon products, in addition to BaO and CuO. The intended oxidant Me3NO shows no great tendency to oxidize Cu(I).
After consulting a lot of data, we found that this compound(75732-01-3)Reference of Mesitylcopper(I) can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com