Tsuda, Tetsuo; Yazawa, Tetsuo; Watanabe, Katsuhiko; Fujii, Tomoyuki; Saegusa, Takeo published the article 《Preparation of thermally stable and soluble mesitylcopper(I) and its application in organic synthesis》. Keywords: mesitylcopper; copper mesityl; lithium alkyl cuprate reagent; amide copper; alkoxide copper; mercaptide copper.They researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Application of 75732-01-3. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:75732-01-3) here.
Mesitylcopper(I) (I) was prepared and isolated by the reaction of mesitylmagnesium bromide and CuCl. I is a unique organocopper(I) compound, which is thermally stable up to 100° and is highly soluble in common organic solvents. I may be utilized in organic synthesis as an efficient metalation reagent and as a useful “”holding group”” in mixed lithium cuprate reagents. I metalated amine, alc. and mercaptan to produce Cu(I) amide, alkoxide and mercaptide, resp. I reacted with alkyllithium (RLi) to form a soluble mixed cuprate reagent II, which effected a selective conjugate addition of the R group to cyclohexenone and trans-2-hexenal. A reagent produced by the reaction of I and LiAlH4 effected the regioselective 1,4-reduction of cyclohexenone in a mixed solvent of THF and (Me2N)3PO.
After consulting a lot of data, we found that this compound(75732-01-3)Application of 75732-01-3 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com