Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60827-45-4, is researched, SMILESS is OC[C@H](O)CCl, Molecular C3H7ClO2Journal, Heterocycles called A formal synthesis of (+)-α-allokainic acid via sulfanyl radical addition-cyclization reaction, Author is Miyata, Okiko; Ozawa, Yoshiki; Ninomiya, Ichiya; Aoe, Keiichi; Hiramatsu, Hajime; Naito, Takeaki, the main research direction is allokainic acid total synthesis radical cyclization; sulfanyl radical addition cyclization diallylamine; pyrrolidine preparation radical addition cyclization diallylamine.Product Details of 60827-45-4.
Sulfanyl radical addition-cyclization of diallylamine I in the presence of thiophenol and AIBN gave the 2,3,4-trisubstituted pyrrolidines II (R = PhSCH2, R1 = H; R = H, R1 = PhSCH2) which were effectively converted into the known key intermediate for the synthesis of (+)-α-allokainic acid via conversion of the phenylsulfanylmethyl group into the isopropenyl group at the 4-position.
In some applications, this compound(60827-45-4)Product Details of 60827-45-4 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com