Stauffer, Molly; Sakhaei, Zeinab; Greene, Christine; Ghosh, Pokhraj; Bertke, Jeffery A.; Warren, Timothy H. published an article about the compound: 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II)( cas:28903-71-1,SMILESS:COC1=CC=C(C=C1)C(C2=[N]3[Co+2]4([N-]56)[N-]7C(C(C8=CC=C(C=C8)OC)=C3C=C2)=CC=C7C(C9=CC=C(C=C9)OC)=C%10C=CC%11=[N]4%10)=C5C=CC6=C%11C%12=CC=C(C=C%12)OC ).Safety of 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:28903-71-1) through the article.
Nitric oxide (NO) is a key signaling mol. in health and disease. While nitrite acts as a reservoir of NO activity, mechanisms for NO release require further understanding. Electronically varied β-diketiminato-copper(II) nitrite complexes [CuII](κ2-O2N) react with a range of electronically tuned triarylphosphines PArZ3 that release NO with the formation of O=PArZ3. Second-order rate constants are largest for electron-poor Cu(II) nitrite and electron-rich phosphine pairs. Computational anal. reveals a transition-state structure energetically matched with exptl. determined activation barriers. The production of NO follows a pathway that involves nitrite isomerization at CuII from κ2-O2N to κ1-NO2 followed by O-atom transfer (OAT) to form O=PArZ3 and [CuI]-NO that releases NO upon PArZ3 binding at CuI to form [CuI]-PArZ3. These findings illustrate important mechanistic considerations involved in NO formation from nitrite via OAT.
In some applications, this compound(28903-71-1)Safety of 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II) is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com