Name: (2S)-(+)-3-Chloropropane-1,2-diol. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: (2S)-(+)-3-Chloropropane-1,2-diol, is researched, Molecular C3H7ClO2, CAS is 60827-45-4, about Porphyrin with circularly polarized luminescence in aggregated states. Author is Wang, Rongqiao; Chen, Shibing; Chen, Qiaoru; Guo, Hongyu; Yang, Fafu.
Porphyrin with circularly polarized luminescence (CPL) in aggregated state was seldom presented due to the strong aggregation-caused quenching (ACQ) effect at aggregation. This work designed and synthesized a novel porphyrin derivative (CPL-P) with good CPL behavior in aggregated states based on the strong AIE-FRET effect and good chirality transfer of liquid crystalline porphyrin, which was constructed by using porphyrin unit as core with four AIE cyanostilbene groups bearing peripheral chiral alkyl chains. CPL-P exhibited orderly hexagonal columnar mesophase between 62.5°C and 113.2°C. It displayed excellent fluorescence emission at 640-760 nm in aggregated states due to the AIE-FRET effect between cyanostilbene unit and porphyrin moiety. Moreover, CPL-P showed the strong CD and CPL properties in aggregated states based on the effective chiral transfer of the spiral liquid crystalline self-assembly. The |glum| value for mesophase attained 6.6 x 10-3 based on the combining effect of AIE-FRET and chiral transfer. This research supplied a new strategy for transferring typical achiral porphyrin with ACQ effect to luminescent mol. with good CPL behavior in aggregated state.
This literature about this compound(60827-45-4)Name: (2S)-(+)-3-Chloropropane-1,2-diolhas given us a lot of inspiration, and I hope that the research on this compound((2S)-(+)-3-Chloropropane-1,2-diol) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com