The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: (2S)-(+)-3-Chloropropane-1,2-diol( cas:60827-45-4 ) is researched.Product Details of 60827-45-4.Song, Yuming; Chen, Huilin; Hu, Xinquan; Bai, Changmin; Zheng, Zhuo published the article 《Highly enantioselective resolution of terminal epoxides with crosslinked polymeric salen-Co(III) complexes》 about this compound( cas:60827-45-4 ) in Tetrahedron Letters. Keywords: kinetic resolution epoxide polymeric cobalt salen complex; asym hydrolysis epoxide polymeric cobalt salen complex. Let’s learn more about this compound (cas:60827-45-4).
Crosslinked polymeric salen-Co(III) complexes derived from a novel dialdehyde and a trialdehyde were synthesized and employed in the hydrolytic kinetic resolution of terminal epoxides. Up to 99% ee was obtained with only 0.16-0.02 mol % of catalyst (based on catalytic unit).
In addition to the literature in the link below, there is a lot of literature about this compound((2S)-(+)-3-Chloropropane-1,2-diol)Product Details of 60827-45-4, illustrating the importance and wide applicability of this compound(60827-45-4).
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com