Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 75732-01-3, is researched, Molecular C9H11Cu, about Toward absolute asymmetric synthesis of coordination polymers with bidentate sulfide ligands, the main research direction is copper halo mesityl sulfide complex preparation crystal structure.Application of 75732-01-3.
In search for sulfide-containing coordination polymers that crystallize as conglomerates, five new copper(I) complexes with prochiral sulfide ligands were prepared and characterized by single crystal x-ray structure determination Three unsym. sulfides were used: Ph propargyl sulfide (Sprop), allyl Me sulfide (Sally), and 2,5-dithiahexane (SS). In [CuCl(Sprop)]n (1), layers are formed via π-coordination of propargyl groups to copper(I). In [Cu2Br2(Sprop)4] (2), discrete dimers form with non-coordinating propargyl groups. In [CuCl(Sally)]n (3), layers are formed via π-coordination of allyl groups to copper(I), but disordered Sally ligands are also found. The mesitylcopper complex [Cu4(Mes)4(Sally)2] (4) is chiral but discrete. In [Cu4(Mes)4(SS)]n (5), racemic chains are formed by the SS ligand. Three out of five complexes prepared thus form coordination polymers, and all of the five complexes (1-5) exhibit terminal sulfide ligands that could be oxidized selectively when incorporated in an enantiopure polymer. Unfortunately none of 1-5 crystallized as a conglomerate, but whether this reflects an inherent tendency in this system is too early to say.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com