Becker, Heinrich; Sharpless, K. Barry published the article 《A new ligand class for the asymmetric dihydroxylation of olefins》. Keywords: asym dihydroxylation olefin anthraquinone ligand; dihydroquinidinylanthraquinone preparation ligand asym dihydroxlation.They researched the compound: (2S)-(+)-3-Chloropropane-1,2-diol( cas:60827-45-4 ).Quality Control of (2S)-(+)-3-Chloropropane-1,2-diol. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:60827-45-4) here.
1,4-Bis(dihydroquinidinyl)- and 1,4-bis(dihydroquininyl)anthraquinone are new ligands which show superior enantioselectivity in the asym. dihydroxylation of almost all olefins having only aliphatic substituents.
Compound(60827-45-4)Quality Control of (2S)-(+)-3-Chloropropane-1,2-diol received a lot of attention, and I have introduced some compounds in other articles, similar to this compound((2S)-(+)-3-Chloropropane-1,2-diol), if you are interested, you can check out my other related articles.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com