Recommanded Product: 75732-01-3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about A tetrameric copper(I) alkoxide with a π-tethered ligand: 2-allyl-6-methylphenoxocopper(I).
The complex 2-allyl-6-methylphenoxocopper(I) has been prepared by reaction between mesitylcopper(I) and 2-allyl-6-methylphenol. Crystallog. studies show that the compound is tetrameric with a distorted cubane-type copper(I)-oxygen core, and with addnl. π-coordination of the ligand to copper through the alkene functionality (ν(C:C) = 1520 cm-1). The ligands thus act both as chelates and as bridges between adjacent copper(I) centers. Copper(I) exhibits trigonal pyramidal coordination geometry with Cu-C distances to the C:C group of 1.976(9) and 2.017(11) Å and Cu-O distances of 1.973(6), 2.021(6) and 2.577(6) Å, resp.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com