Category: iodides-buliding-blocks. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about Anti-Selective Direct Catalytic Asymmetric Aldol Reaction of Thiolactams. Author is Sureshkumar, Devarajulu; Kawato, Yuji; Iwata, Mitsutaka; Kumagai, Naoya; Shibasaki, Masakatsu.
An anti-selective direct catalytic asym. aldol reaction of thiolactams is described. A soft Lewis acid/hard Bronsted base cooperative catalyst comprised of mesitylcopper/(R,R)-Ph-BPE exhibited high catalytic performance to produce an anti-aldol product with high stereoselectivity. The highly chemoselective nature of the present catalysis allows for the use of enolizable aldehydes as aldol acceptors. The diverse transformations of the thiolactam moiety highlight the synthetic utility of the present anti-aldol protocol.
This literature about this compound(75732-01-3)Category: iodides-buliding-blockshas given us a lot of inspiration, and I hope that the research on this compound(Mesitylcopper(I)) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com