The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Mesitylcopper(I)(SMILESS: [Cu]C1=C(C)C=C(C)C=C1C,cas:75732-01-3) is researched.Formula: C4H10Cl2NiO2. The article 《Reversible Redox Cycling of Well-Defined, Ultrasmall Cu/Cu2O Nanoparticles》 in relation to this compound, is published in ACS Nano. Let’s take a look at the latest research on this compound (cas:75732-01-3).
Exceptionally small and well-defined copper (Cu) and cuprite (Cu2O) nanoparticles (NPs) are synthesized by the reaction of mesitylcopper(I) with either H2 or air, resp. In the presence of substoichiometric quantities of ligands, namely, stearic or di(octyl)phosphinic acid (0.1-0.2 equiv vs. Cu), ultrasmall nanoparticles are prepared with diameters as low as ∼2 nm, soluble in a range of solvents. The solutions of Cu NPs undergo quant. oxidation, on exposure to air, to form Cu2O NPs. The Cu2O NPs can be reduced back to Cu(0) NPs using accessible temperatures and low pressures of hydrogen (135 °C, 3 bar H2). This striking reversible redox cycling of the discrete, solubilized Cu/Cu(I) colloids was successfully repeated over 10 cycles, representing 19 sep. reactions. The ligands influence the evolution of both composition and size of the nanoparticles, during synthesis and redox cycling, as explored in detail using vacuum-transfer aberration-corrected transmission electron microscopy, XPS, and visible spectroscopy.
This literature about this compound(75732-01-3)Application In Synthesis of Mesitylcopper(I)has given us a lot of inspiration, and I hope that the research on this compound(Mesitylcopper(I)) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com