The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II)( cas:28903-71-1 ) is researched.Application of 28903-71-1.Chen, Chen; Zuo, Huiping; Chan, Kin Shing published the article 《Catalytic hydrodebromination of aryl bromides by cobalt tetra-butyl porphyrin complex with EtOH》 about this compound( cas:28903-71-1 ) in Tetrahedron. Keywords: cobalt porphyrin complex catalyst hydrodebromination aryl bromide ethanol. Let’s learn more about this compound (cas:28903-71-1).
Hydrodebromination of aryl bromides catalyzed by electron rich and sterically unhindered cobalt 5,10,15,20-tetrabutylporphyrin was achieved at mild conditions in good yields employing EtOH as the hydrogen source. The catalytic efficiency was enhanced compared with previously reported cobalt tetra-aryl porphyrin catalysts. A revised mechanism of single electron transfer was proposed.
As far as I know, this compound(28903-71-1)Application of 28903-71-1 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com