The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Mesitylcopper(I)(SMILESS: [Cu]C1=C(C)C=C(C)C=C1C,cas:75732-01-3) is researched.HPLC of Formula: 56413-95-7. The article 《Bis(2-phenylethyl)-nacnac: A Chiral Diketiminate Ligand and Its Copper Complexes》 in relation to this compound, is published in Organometallics. Let’s take a look at the latest research on this compound (cas:75732-01-3).
The chiral diketiminate ligand bis-N,N’-(2-phenylethyl)-2,4-diiminopentane, 1H, was synthesized in good yields in a 1-step reaction from chiral amine and acetylacetone. Reaction of 1Li(THF) with N-bromosuccinimide yielded the succinimide-substituted ligand 2H. Cu complexes were obtained by reaction of the ligand with a basic Cu source in the presence of coordinating Lewis bases, and 1Cu(NCMe), 1Cu(DMAP), 1Cu(PPh3), 1Cu(2,6-xylyl isonitrile), 2Cu(PPh3), and 2Cu(2,6-xylyl isonitrile) were prepared and, for the most part, characterized by x-ray diffraction studies. Compared to their more common analogs with aromatic substituents on N, 1 and 2 seem to be more basic (1 > 2) and sterically more demanding (2 > 1). Their Cu complexes are less stable than those of aryl-substituted diketiminates and tend to decompose by disproportionation, most probably after dissociation of the coordinated Lewis base. Despite the rotational freedom around the N-R* bond, the complexes are sterically rigid, a necessary requirement for potential applications in enantioselective catalysis.
From this literature《Bis(2-phenylethyl)-nacnac: A Chiral Diketiminate Ligand and Its Copper Complexes》,we know some information about this compound(75732-01-3)Name: Mesitylcopper(I), but this is not all information, there are many literatures related to this compound(75732-01-3).
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com