So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Cavazzini, Marco; Quici, Silvio; Pozzi, Gianluca researched the compound: (2S)-(+)-3-Chloropropane-1,2-diol( cas:60827-45-4 ).Product Details of 60827-45-4.They published the article 《Hydrolytic kinetic resolution of terminal epoxides catalyzed by fluorous chiral Co(salen) complexes》 about this compound( cas:60827-45-4 ) in Tetrahedron. Keywords: kinetic resolution epoxide perfluoroalkyl salen cobalt catalyst. We’ll tell you more about this compound (cas:60827-45-4).
Cobalt complexes of fluorous chiral salen ligands have been synthesized and tested as catalysts in the hydrolytic kinetic resolution of terminal epoxides. Whereas the activity of heavily fluorinated complexes was found to be rather low, a light fluorous complex I was shown to be an efficient and highly selective catalyst for this asym. ring-opening reaction. Several strategies for the isolation of reaction products and the recovery of the fluorous catalyst are also discussed.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com