Month: March 2022

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 75732-01-3, is researched, SMILESS is [Cu]C1=C(C)C=C(C)C=C1C, Molecular C9H11CuJournal, Topics in Catalysis called Bimetallic Ru-Cu Nanoparticles Synthesized in Ionic Liquids: Kinetically Controlled Size and Structure, Author is Arquilliere, Philippe P.; Helgadottir, Inga S.; Santini, Catherine C.; Haumesser, Paul-Henri; Aouine, Mimoun; Massin, Laurence; Rousset, Jean-Luc, the main research direction is bimetallic ruthenium copper nanoparticle ionic liquid kinetically control.Category: iodides-buliding-blocks.

The authors report a new synthesis of size-controlled bimetallic Ru-Cu nanoparticles (NPs) in ionic liquids using two organometallic precursors. Enough, upon mixing ruthenium and copper precursors, smaller bimetallic NPs (1.9-2.8 nm) are formed as compared to single metals (Cu: 5 nm; Ru: 4 nm) in a large range of copper molar fractions (χCu = 0.005-0.91). Surface and microscopy techniques evidence that NPs have metallic copper on the surface and crystalline hcp. metallic ruthenium core. This structure is further assessed by the catalytic activity of the bimetallic NPs, showing that conversion of benzene in cyclohexane is reduced with increasing χCu.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Li, Haiyan; Sundararaman, Anand; Venkatasubbaiah, Krishnan; Jakle, Frieder published an article about the compound: Mesitylcopper(I)( cas:75732-01-3,SMILESS:[Cu]C1=C(C)C=C(C)C=C1C ).Quality Control of Mesitylcopper(I). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:75732-01-3) through the article.

Side group diarylboryl substituted polythiophenes through silicon-boron exchange were synthesized. It was found that all the synthesized polymers are strongly colored. Varying the aryl substitution on boron can tailor the photophys. behavior. Thus, their potential applications in electronic devices and as sensor materials are under investigation.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

COA of Formula: C3H7ClO2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: (2S)-(+)-3-Chloropropane-1,2-diol, is researched, Molecular C3H7ClO2, CAS is 60827-45-4, about Study on synthesis and properties of chloride-[1-ethyl-3-(1,2-dihydroxypropyl)]imidazole ionic liquid.

A method for the synthesis of the title compound is reported here. A chiral imidazole ionic liquid was prepared from 1-ethylimidazole and (2S)-3-chloro-1,2-propanediol. The resulting chiral ionic liquid was characterized by NMR. Its elec. conductivity in different solvents was determined The result shows that the ionic liquid can be dissolved in acetonitrile, acetone, ethanol, water, N, N-dimethylformamide (DMF) but not in Et acetate. The elec. conductivity of the ionic liquid is also measured at different temperatures and concentrations, and the result shows that the elec. conductivity value increases along with concentration and temperature, and the value of elec. conductivity K is different in different solvents. Its order is as follow: K(acetonitrile)=K(water)>K(DMF)>K(acetone)>K.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60827-45-4, is researched, SMILESS is OC[C@H](O)CCl, Molecular C3H7ClO2Journal, International Journal of Andrology called Inhibition of glucose catabolism in rat, hamster, rhesus monkey and human spermatozoa by α-chlorohydrin, Author is Ford, W. C. L.; Harrison, Anne; Takkar, G. L.; Waites, G. M. H., the main research direction is sperm glucose metabolism chlorohydrin; glycolysis sperm chlorohydrin.Electric Literature of C3H7ClO2.

Spermatozoa from the cauda epididymis of rats treated with RS-α-chlorohydrin [96-24-2] (10 mg/kg/day for 7 days, orally) had the same ATP [56-65-5] content as control spermatozoa immediately after collection, but were unable to metabolize glucose [50-99-7] in vitro and so their ATP content declined more rapidly than that of control spermatozoa. The in vitro metabolism of glucose by spermatozoa from rat, hamster, rhesus monkey, and human was inhibited by ≥80% after 15-30 min preincubation in the presence of RS-α-chlorohydrin concentrations of <1, >10, 5-10, and >50 mM, resp. Inhibition of glucose oxidation was correlated with a reduction in ATP concentration in the spermatozoa. α-Chlorohydrin may act as an antifertility agent by inhibition of sperm glycolysis, but RS-α-chlorohydrin would apparently not be an effective contraceptive in man. However, the glucose metabolism of human spermatozoa was significantly inhibited by <10 mM of S-α-chlorohydrin [60827-45-4]. Here is a brief introduction to this compound(60827-45-4)Electric Literature of C3H7ClO2, if you want to know about other compounds related to this compound(60827-45-4), you can read my other articles.

Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Chandrasekaran, M.; Krishnan, V. researched the compound: 2-Methylglutaronitrile( cas:4553-62-2 ).Recommanded Product: 4553-62-2.They published the article 《Electrochemical reduction of 2-methylglutaronitrile on deposited electrodes in aqueous media》 about this compound( cas:4553-62-2 ) in Bulletin of Electrochemistry. Keywords: electrochem reduction methylglutaronitrile; methyldiaminopentane. We’ll tell you more about this compound (cas:4553-62-2).

H2N(CH2)3CHMeCH2NH2 was obtained in 40-60% yield by the electrochem. reduction of NCCH2CH2CHMeCN using deposited nickel black and palladium black cathodes under different conditions. Various synthetic parameters were standardized. The results obtained from various reduction experiments are discussed.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Formula: C6H8N2. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 2-Methylglutaronitrile, is researched, Molecular C6H8N2, CAS is 4553-62-2, about New solvent for aromatics separation. Author is Feldman, Julian.

1,3-Dicyanobutane (derived from acrylonitrile) has a higher capacity for light aromatic hydrocarbons in liquid-liquid extraction than does sulfolane. As a solvent in extractive distillation its low volatility, high thermal stability, low f.p. and high selectivity are useful. Equilibrium data and multistage extractions of a typical light catalytic reformate are reported. A light counter-solvent is effective, especially when followed by extractive distillation A combination of methods gives high purity aromatics or improved octane gasoline. A flow diagram is given for continuous cyclic operation to sep. reformate and recover the solvent.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: (2S)-(+)-3-Chloropropane-1,2-diol, is researched, Molecular C3H7ClO2, CAS is 60827-45-4, about The selective neurotoxicity produced by 3-chloropropanediol in the rat is not a result of energy deprivation.Related Products of 60827-45-4.

The biochem. mechanism of toxicity of the exptl. astrocyte neurotoxicant and food contaminant S-3-chloro-1,2-propanediol (3-CPD) has been proposed to be via inhibition of glyceraldehyde-3-phosphate dehydrogenase (GAPDH). We have confirmed this action in liver, which shows inhibition to 6.0±0.7% control at the neuropathic dose of 140 mg/kg. However, GAPDH activity in brain only fell to a min. of 54±24% control, and the concentrations of lactate and pyruvate (the downstream products of GAPDH), showed no pre-neuropathic decreases in 3-CPD susceptible brain tissue. There was no inhibition of GAPDH activity in primary astrocyte cultures at sub-cytotoxic exposures. We therefore sought alternative mechanisms to explain its toxicity to astrocytes. We were able to show that 3-CPD is a substrate for glutathione-S-transferase and also that, after bioactivation by alc. dehydrogenase, it generates an irreversible inhibitor of glutathione reductase. In addition, incubation of brain slices from the 3-CPD-vulnerable inferior colliculus produces a depletion of glutathione and an inhibition of glutathione-S-transferase that is not seen in equivalent slices taken from the 3-CPD-resistant occipital neocortex. A smaller but significant and similarly regionally selective decrease in glutathione content is also seen in vivo. We conclude that 3-CPD does not produce its astrocytic toxicity via energy deprivation, and suggest that selective bioactivation and consequent disruption of redox state is a more likely mechanism.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called High-throughput screening of pesticide and veterinary drug residues in baby food by liquid chromatography coupled to quadrupole Orbitrap mass spectrometry, published in 2014-06-20, which mentions a compound: 23307-72-4, Name is Sodium ((4-aminophenyl)sulfonyl)(6-chloropyrazin-2-yl)amide, Molecular C10H8ClN4NaO2S, Product Details of 23307-72-4.

A new anal. method was developed and validated for simultaneous anal. of 333 pesticide and veterinary drug residues in baby food. Response surface methodol. was employed to optimize a generic extraction method. Ultrahigh-performance liquid chromatog. and electrospray ionization quadrupole Orbitrap high-resolution mass spectrometry (UHPLC-ESI Q-Orbitrap) was used for the separation and detection of all the analytes. The method was validated by taking into consideration the guidelines specified in Commission Decision 2002/657/EC and SANCO/12571/2013. The extraction recoveries were in a range of 79.8-110.7%, with coefficient of variation <8.3%. The 333 compounds behave dynamic in the range 0.1-1000 μg kg-1 concentration, with correlation coefficient >0.99. The limits of detection for the analytes are in the range 0.01-5.35 μg kg-1. The limits of quantification for the analytes are in the range 0.01-9.27 μg kg-1. This method has been successfully applied on screening of pesticide and veterinary drugs in ninety-three com. baby food samples, and tilmicosin, fenbendazole, tylosin tartrate and thiabendazole were detected in some samples tested in this study. The present study is very useful for fast screening of different food contaminants.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Hu, Ji; Malic, Nino; Scott, Janet L.; Strauss, Christopher R. published the article 《Potential impacts of deep-sea injection of CO2 on marine organic chemistry》. Keywords: deep sea injection carbon dioxide effect marine organic chem; carbon dioxide epoxide effect marine organic chem seawater injection.They researched the compound: (2S)-(+)-3-Chloropropane-1,2-diol( cas:60827-45-4 ).Quality Control of (2S)-(+)-3-Chloropropane-1,2-diol. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:60827-45-4) here.

The extent of reaction of epoxides in salt water changed markedly following introduction of gaseous or liquid CO2. Higher concentrations of β-chlorohydrins in carbonated salt water vs. concentrations in salt water alone were attributed to greater acidity of the aqueous phase. This suggested regimes for sequestering CO2 by deep sea injection should account for potential effects on marine organic chem. No evidence was obtained for enhanced nucleophilicity of Cl- through potential desolvation at the CO2-water interface.

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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com

Reference of 6,7-Dichlorobenzo[d]thiazol-2-amine. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 6,7-Dichlorobenzo[d]thiazol-2-amine, is researched, Molecular C7H4Cl2N2S, CAS is 25150-27-0, about Antiparasitic thiocyanatobenzothiazoles. Author is Alaimo, Robert J.; Pelosi, Stanford S.; Hatton, Christopher J.; Gray, Joseph E..

A series of 7 title compound was prepared by the reaction of the appropriate aniline derivative with thiocyanogen [505-14-6] generated in situ followed by thermal cyclization. The activity of 2-amino-6-ethyl-4-thiocyanatobenzothiazole (I) [37069-20-8] against Ascaris suum and Hymenolepis nana in mice was comparable to that of dl-tetramisole [5036-02-2] and bunamidine [3748-77-4], resp. 2-Amino-7-chloro-6-fluoro-4-thiocyanatobenzothiazole (II) [37525-33-0] and 2-amino-6,7-dichloro-4-thiocyanatobenzothiazole (III) [37069-18-4] were active in vitro against several yeast species, including Candida albicans and Microsporum canis.

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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem