So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Robinson, Thomas P.; Price, Richard D.; Davidson, Matthew G.; Fox, Mark A.; Johnson, Andrew L. researched the compound: Mesitylcopper(I)( cas:75732-01-3 ).Recommanded Product: 75732-01-3.They published the article 《Why are the {Cu4N4} rings in copper(I) phosphinimide clusters [Cu{μ-N:PR3}]4 (R = NMe3 or Ph) planar?》 about this compound( cas:75732-01-3 ) in Dalton Transactions. Keywords: crystal structure optimized tetrameric cyclic copper phosphinimide preparation; mol structure optimized tetrameric cyclic copper phosphinimide preparation. We’ll tell you more about this compound (cas:75732-01-3).
The Cu phosphinimide complexes [Cu{μ-N:PR3}]4 (1, R = NMe2 and 2, R = Ph) were obtained in good yields from the reactions of Cu[Mes] (Mes = mesityl, C6H2Me3-2,4,6) with the corresponding iminophosphoranes, HNPR3. The mol. structures of 1 and 2 reveal planar eight-membered {Cu4N4} rings which contrasts with the saddle-shaped {M4N4} rings found in related metal phosphinimide complexes. According to computations, there is negligible aromaticity in the planar {Cu4N4} rings in 1 and 2 and the saddle shape observed in related {M4N4} rings is due to steric factors.
There is still a lot of research devoted to this compound(SMILES:[Cu]C1=C(C)C=C(C)C=C1C)Recommanded Product: 75732-01-3, and with the development of science, more effects of this compound(75732-01-3) can be discovered.
Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com