Name: 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 5,10,15,20-Tetrakis (4-methoxyphenyl)-21H,23H-porphine cobalt (II), is researched, Molecular C48H38CoN4O4, CAS is 28903-71-1, about Inductive and electrostatic effects on cobalt porphyrins for heterogeneous electrocatalytic carbon dioxide reduction. Author is Zhu, Minghui; Yang, Deng-Tao; Ye, Ruquan; Zeng, Joy; Corbin, Nathan; Manthiram, Karthish.
Electrochem. carbon dioxide reduction enables conversion of carbon dioxide into fuels and chems. with renewable energy input. Cobalt-based mol. complexes have exhibited high selectivity, activity, and stability for transforming carbon dioxide into carbon monoxide. Through evaluating immobilized cobalt porphyrins functionalized with various peripheral substituents, we demonstrated that their activity is affected not only by the electronegativity of the substituents, but importantly, also by the charge of the substituents. The performance of immobilized cobalt porphyrins can be improved by introducing electron-donating and pos. charged functional groups. Through kinetic studies, we were able to understand the mechanism by which electron-donating groups enhance the observed rates of carbon dioxide reduction and how cationic functionality may contribute towards electrostatic stabilization of the intermediate formed in the rate-determining step. Our methodol. provides a robust and exptl.-verified method of computationally predicting the electronic effect of peripheral substitution and hence the catalytic activity of substituted porphyrins.
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Reference:
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