The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Ethyl 4-amino-1-methyl-1H-imidazole-2-carboxylate hydrochloride, is researched, Molecular C7H12ClN3O2, CAS is 180258-46-2, about Benzoisothiazolone Organo/Copper-Cocatalyzed Redox Dehydrative Construction of Amides and Peptides from Carboxylic Acids using (EtO)3P as the Reductant and O2 in Air as the Terminal Oxidant, the main research direction is amide peptide preparation; benzoisothiazolone preparation cocatalyst copper redox dehydrative amidation.Computed Properties of C7H12ClN3O2.
Carboxylic acids and amine/amino acid reactants can be converted to amides and peptides at neutral pH within 5-36 h at 50° using catalytic quantities of a redox-active benzoisothiazolone and a copper complex. These catalytic “”oxidation-reduction condensation”” reactions are carried out open to dry air using O2 as the terminal oxidant and a slight excess of tri-Et phosphite as the reductant. Tri-Et phosphate is the easily removed byproduct. These simple-to-run catalytic reactions provide practical and economical procedures for the acylative construction of C-N bonds.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com