The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Mesitylcopper(I)( cas:75732-01-3 ) is researched.Synthetic Route of C9H11Cu.Gustafsson, Bjoern; Hakansson, Mikael; Jagner, Susan published the article 《Copper(II) is harder than copper(I): a novel mixed-valence example from alkoxide chemistry》 about this compound( cas:75732-01-3 ) in New Journal of Chemistry. Keywords: copper mixed valence trinuclear allyl phenoxide preparation; phenol allyl methyl copper mixed valence trinuclear complex; alkene copper mixed valence trinuclear complex allylphenolate; crystal structure copper mixed valence trinuclear allyl methyl phenoxide; mol structure copper mixed valence trinuclear allyl methyl phenoxide. Let’s learn more about this compound (cas:75732-01-3).
Partial oxidation or disproportionation of tetrameric 2-allyl-6-methylphenoxocopper(I) leads to the formation of a novel trinuclear mixed-valence Cu(I)/Cu(II) alkoxide [Cu3[μ-η2-OC6H3-6-Me-2-(CH2CH:CH2)-κO]4], in which the central copper(II) atom is coordinated in a distorted square-planar configuration by four μ-oxide ligands, whereas the peripheral copper(I) centers are each bonded to two C:C groups and two μ-oxide ligands in a tetrahedral arrangement.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com