The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Mesitylcopper(I), is researched, Molecular C9H11Cu, CAS is 75732-01-3, about Direct Synthesis of N-Heterocyclic Carbene-Stabilized Copper Nanoparticles from an N-Heterocyclic Carbene-Borane, the main research direction is nitrogen heterocyclic carbene stabilized copper nanoparticle preparation; borane nitrogen heterocyclic carbene reaction copper complex; mesityl copper reaction didodecylimidazolium bromide borane adduct; carbene ligands; copper; nanoparticles; radical reactions; reaction mechanisms.SDS of cas: 75732-01-3.
N-Heterocyclic carbene (NHC)-stabilized copper nanoparticles (NPs) were synthesized from an NHC-borane adduct and mesitylcopper(I) under thermal conditions (refluxing toluene for 2.5 h). NPs with a size distribution of 11.6±1.8 nm were obtained. The interaction between Cu NPs and NHC ligands was probed by XPS, which showed covalent binding of the NHC to the surface of the NPs. Mechanistic studies suggested that NHC-borane plays two roles: contributing to the reduction of [CuMes]2 to release Cu0 species and providing NHC ligands to stabilize the copper NPs.
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Reference:
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com