Application of 375-80-4, The chemical industry reduces the impact on the environment during synthesis 375-80-4, name is 1,6-Diiodoperfluorohexane, I believe this compound will play a more active role in future production and life.
11.1 g (0.02 mol) of IC 6 F 12 I obtained in Reference Example 1, 0.16 g (0.001 mol) of ferric chloride FeCl 3 and 15 g of acetonitrile were added to a reactor having a capacity of 150 ml equipped with a stirrer and a thermometer. Next, VDF was added under reduced pressure until reaching 0.5 MPa, and the mixture was heated at 130 C. for 14 hours. A total amount of 3.2 g (0.05 mol) of VDF was fed to the reactor.After cooling and discharging the remaining gas, 6.1 g (0.04 mol) of 1,8-diazabicyclo [5.4.0] -7-undecene was added to this product and the reaction was carried out at 10 C. for 3 hours. After adding 30 g of water and 8 g of a 20% hydrochloric acid aqueous solution to the obtained reaction solution, acetonitrile was distilled off. Further, 40 g of chloroform was added, and an organic layer was obtained by liquid separation operation.Distillation of chloroform from the organic layer was followed by distillation to obtain 1.4 g (yield 16%) of a 6E-T 2 T fraction (purity 99%) having a boiling point of 76 C. (13.33 kPa) of the formula (12)3.4 g (yield 35%) of 6E-1 T fraction (purity 97%) having a boiling point of 63 C. (4.00 kPa) of the formula (13) was obtained.
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 1,6-Diiodoperfluorohexane, other downstream synthetic routes, hurry up and to see.
Reference:
Patent; Tosoh F-Tech Co., Ltd.; Kondo, Norihisa; Kono, Masahiro; (14 pag.)JP2015/81232; (2015); A;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com