Electric Literature of 7681-82-5, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 7681-82-5 name is Sodium iodide, This compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.
General procedure: We used a simple method (branched tube glass) in order to design and preparation of suitable single crystals for X-ray diffraction. The one-pot reaction of a 1:1 M ratio of Cd(II) salts and L in the mixture of EtOH and MeOH afforded the compounds 1-3 in good yields. Cd(NO3)2ยท4H2O (0.154g, 0.5mmol), NaHal (Hal=Cl, 0.058g; Br, 0.103g; I, 0.150g; 1mmol) and the ligand L (0.208g, 0.5mmol) were placed in the main arm of a branched tube. A mixture of MeOH (7.5mL) and EtOH (7.5mL) was carefully added to fill the arms. The tube was sealed and immersed in an oil bath at 60C while the branched arm was kept at ambient temperature. X-ray suitable crystals were formed during the next days in the cooler arm and were filtered off, washed with acetone and diethyl ether, and dried in air.
At the same time, in my other blogs, there are other synthetic methods of this type of compound, Sodium iodide, and friends who are interested can also refer to it.
Reference:
Article; Akbari Afkhami, Farhad; Mahmoudi, Ghodrat; White, Jonathan M.; Lipkowski, Janusz; Konyaeva, Irina A.; Safin, Damir A.; Inorganica Chimica Acta; vol. 484; (2019); p. 481 – 490;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com