Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 355-43-1, name is 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane, This compound has unique chemical properties. The synthetic route is as follows., COA of Formula: C6F13I
In a 1000 mL four-necked flask equipped with a mechanical stirrer, a thermometer, and a condenser, 446 g (1 mol) of perfluorohexyl iodide was added.240.2 g (1.0 mol) of sodium sulfide nonahydrate, heated to a temperature of 90 C by stirring;Another 500mL three-neck bottle with a bottom drop device, mechanical agitation, and a condenser tube.3.4 g (moisture content 28%, 0.01 mol) of benzoyl peroxide and 117.8 g (1.05 mol) of n-octene were added in advance at room temperature.Stir well, add a mixture of benzoyl peroxide and n-octene to a 1000 mL four-necked flask at a temperature of 90 C.Control the dropping time for 2.0 hours, control the dropping reaction temperature to 90 C, and add dropwise.The reaction was kept at 90 C for 1.0 hour, the reaction was completed, the temperature was lowered to room temperature, the insoluble matter was removed by filtration, and distilled under reduced pressure.Obtaining 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodotetradecane 548.0 g, content 99.1%, yield 97.3%;Wherein the isomers were 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-7-iodomethyltridecane at a content of 0.9%.
Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of 355-43-1.
Reference:
Patent; Zhejiang Xinhecheng Co., Ltd.; Zhejiang Xinhecheng Pharmaceutical Co., Ltd.; He Jiawei; Qian Hongsheng; Hu Ruijun; Lu Guobin; Zhang Yangyang; Zhang Wenzhi; Zhu Xinjun; Xu Yong; (10 pag.)CN108358747; (2018); A;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com