Adding a certain compound to certain chemical reactions, such as: 7681-82-5, name is Sodium iodide, belongs to iodides-buliding-blocks compound, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound 7681-82-5, Recommanded Product: 7681-82-5
NaI (73 mg, 0.487 mmol) in CH2Cl2 (5 ml) was added to[Ni(Cl2(Lbenz)] 3a (90 mg, 121 mmol) in CH2Cl2 (10 ml). The mixturewas stirred 24 h, was filtered over Celite and was concentrated by volume to afford 100mg (90%) of 3c as a red solid that was isolatedby filtration. 1H NMR (CDCl3): d 7.62 (d, J 7.2, ortho, 4H, -C6H5),7.40 (t, J 7.6, meta, 4H, -C6H5), 7.31 (t, J 7.6, para, 2H, -C6H5),7.19e7.22 (m, 4H, benzimi -CH]CH), 7.13e7.15 (m, 4H, benzimi),5.29 (bs, 8H, -benzimi-NCH2), 3.75 (s, 4H, -NCH2Ph), 3.11 (bs, 8H,PhCH2CH2CH2), 2.59 (t, J 5.6, 8H, CH2NCH2Ph). 13C NMR (CD2Cl2):d 190.4, 141, 136, 129.5, 128.8, 127, 122, 109.6, 60, 54, 46, 30, 28. 13CNMR (CDCl3): d 190, 140, 136, 129, 128.7, 127, 122, 109, 59.5, 53, 46,27. HR FT-ICR MS: found 462.0680 (calcd for C40H46I2N6NiH, m/z[3c H]2 462.0686).
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Reference:
Article; Thapa, Rajesh; Kilyanek, Stefan M.; Journal of Organometallic Chemistry; vol. 901; (2019);,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com