Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 507-63-1, Name is Heptadecafluoro-1-iodooctane, SMILES is IC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F, in an article , author is Huebner, L, once mentioned of 507-63-1, Computed Properties of C8F17I.
Heterometallic lanthanide group 12 metal iodides
Neodymium tri-iodide reacts with Group 12 metal (M; M = Zn, Cd, Hg) iodides to form heterometallic compounds. These Lewis acidic M cleave Nd-I bonds to give either ionic {[(THF)(5)NdI2][MI3THF]; M = Zn, Cd} or charge-neutral {(THF)(5)NdI(mu(2)I)HgI3} compounds. Differences in structure are interpreted primarily in terms of M-L bond strengths, rather than Nd-L bond strengths. Experiments with Yb indicate that if there is any excess iodide present in these syntheses then the most readily isolated product is a triiodide salt, i.e., [(THF)(5)Yb-2][I-3]. In conventional solvents the presence of Lewis acid is not required for iodide displacement-from pyridine, YbI3 crystallizes as [(py)(5)YbI2][I]. These compounds are potentially useful as heterometallic sources of lanthanide-doped iodide matrixes, they illustrate the ease with which iodides are displaced from lanthanide coordination spheres, and they underscore the complexity associated with using lanthanide iodides as Lewis acid catalysts.
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