Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 3058-39-7, Name is 4-Iodobenzonitrile. In a document, author is Voronkov, M. G., introducing its new discovery. HPLC of Formula: C7H4IN.
Acyl Iodides in Organic Synthesis. Reaction of Acetyl Iodide with Thiols
The direction of reactions of acetyl iodide with aliphatic, aromatic, and heterocyclic thiols is determined by the thiol acidity and steric factors. Acetyl iodide reacted with aliphatic thiols, including trialkylsilyl-substituted derivatives R(CH2)(n)SH (R = Me, n = 3; R = Me3Si, n = 3; R = Et3Si, n = 2), to give the corresponding ethanethioates R(CH2)(n)SCOMe. Benzenethiol was oxidized with acetyl iodide to diphenyl disulfide. The reaction of acetyl iodide with 2-sulfanylethanol afforded 2-(2-iodoethyldisulfanyl)ethyl acetate as a result of three consecutive-parallel processes: acylation, iodination, and oxidation of the initial compound. 1,3-Benzothiazole-2-thiol reacted with acetyl iodide only at the nitrogen atom to give quaternary salt, whereas the SH group remained intact.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 3058-39-7 help many people in the next few years. HPLC of Formula: C7H4IN.