Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 460-37-7, Name is 1,1,1-Trifluoro-3-iodopropane, molecular formula is C3H4F3I. In an article, author is Leigh, GJ,once mentioned of 460-37-7, Name: 1,1,1-Trifluoro-3-iodopropane.
The use of trimethylsilyl iodide as a synthon in coordination chemistry
Trimethylsilyl iodide is shown to be an efficient metathetical reagent for preparing transition-metal iodides from the corresponding chlorides. though often complications can cause problems. These include reduction of the starting metal chloride when its oxidation state is high, due to the reaction of iodide, and even oxidation of low-oxidation-state compounds, presumably by incipient silyl cations. Finally, some very inert chlorides, such as of iridium(III), react too slowly with the iodide under the experimental conditions, and simple reaction with solvent becomes predominant. (C) 2002 Elsevier Science B.V. All rights reserved.
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