Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 3058-39-7, Name is 4-Iodobenzonitrile, molecular formula is , belongs to iodides-buliding-blocks compound. In a document, author is Cadge, Jamie A., HPLC of Formula: C7H4IN.
Oxidative Addition of Alkenyl and Alkynyl Iodides to a Au-I Complex
The first isolated examples of intermolecular oxidative addition of alkenyl and alkynyl iodides to Au-I are reported. Using a 5,5 ‘-difluoro-2,2 ‘-bipyridyl ligated complex, oxidative addition of geometrically defined alkenyl iodides occurs readily, reversibly and stereospecifically to give alkenyl-Au-III complexes. Conversely, reversible alkynyl iodide oxidative addition generates bimetallic complexes containing both Au-III and Au-I centers. Stoichiometric studies show that both new initiation modes can form the basis for the development of C-C bond forming cross-couplings.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3058-39-7, in my other articles. HPLC of Formula: C7H4IN.