In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 69113-59-3 as follows. Product Details of 69113-59-3
General procedure: Vial (C2) was loaded with aryl iodide/bromide (0.5 mmol), Pd(PPh3)4 (29 mg, 5 mol %), Et3N(139 muL, 1 mmol) and cyanamide (63 mg, 1.5 mmol). To vial (C1) was added Mo(CO)6 (138mg, 0.5 mmol) and thereafter 1,4-dioxane (3+3 mL) was added to C1 and C2. The two vials were capped with a gas tight cap and DBU (224 muL, 1.5 mmol) was added to C1. The sealed double vial was heated in a heat-block (65 C for iodides and 85 C for bromides) for 20 h with vigorous stirring.
According to the analysis of related databases, 69113-59-3, the application of this compound in the production field has become more and more popular.
Reference:
Article; Mane, Rajendra S.; Nordeman, Patrik; Odell, Luke R.; Larhed, Mats; Tetrahedron Letters; vol. 54; 50; (2013); p. 6912 – 6915;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com