Electric Literature of 16355-92-3,Some common heterocyclic compound, 16355-92-3, name is 1,10-Diiododecane, molecular formula is C10H20I2, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.
EXAMPLE 11 N, N’-Decane-1, 10-diyl-bis-quinolinium Diiodide (bQDI).; 1, 10-Diiododecane (mmol) was added to a solution (30 mL) of dry quinoline, and the solution heated for 24 hours at 65 OC. The resulting precipitate was filtered, and the product washed five times with dry diethyl ether. The resulting yellow solid was isolated in a 91% yield. ‘H NMR (300 MHz, DMSO-D6) 8 9.53 (1H, d, C2-H), 9.29 (1H, d, C3-H), 8.61 (1H, d, C8-H), 8. 50 (1H, d, C4-H), 8.29 (1H, t, C7-H), 8.18 (1H, t, C5-H), 8.06 (1H, d, C6-H), 5.04 (2H, t, C’1- CH2), 1.96 (2H, m, C’2-CH2), 1.32 (6H, m, C’3-5-CH2) ; 13C NMR (75 MHz, DMSO-D6) 8 149.5, 147.4, 137.4, 135.6, 130.7, 129. 9,129. 7,122. 1,118. 9,57. 3,29. 5,28. 9,28. 5, 25. 7.
These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route 1,10-Diiododecane, its application will become more common.
Reference:
Patent; UNIVERSITY OF KENTUCKY RESEARCH FOUNDATION; WO2005/66129; (2005); A2;,
Iodide – Wikipedia,
Iodide – an overview | ScienceDirect Topics – ScienceDirect.com